On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1999, Volume: 66, Number: 2, Pages: 337-341 Pages count : 5 DOI: 10.1007/BF02475810 | ||||||||
Tags | Klaus reaction, Mechanism of catalytic redox reactions, Methanol synthesis, Selective reduction of nitrogen oxides by hydrocarbons, Strongly bound intermediates | ||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 95-03-09622 |
2 | Russian Foundation for Basic Research | 95-03-09675 |
Abstract:
The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.
Cite:
Sadykov V.A.
, Rozovskii A.Y.
, Lunin V.V.
, Lin G.I.
, Alikina G.M.
, Buchtiyarova G.A.
, Zolotovskii B.P.
, Beloshapkin S.A.
On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions
Reaction Kinetics and Catalysis Letters. 1999. V.66. N2. P.337-341. DOI: 10.1007/BF02475810 WOS Scopus РИНЦ
On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions
Reaction Kinetics and Catalysis Letters. 1999. V.66. N2. P.337-341. DOI: 10.1007/BF02475810 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 13, 1998 |
Accepted: | Jan 11, 1999 |
Published print: | Mar 1, 1999 |
Identifiers:
Web of science | WOS:000079504700021 |
Scopus | 2-s2.0-0037528746 |
Elibrary | 13307172 |
Chemical Abstracts | 1999:613472 |
Chemical Abstracts (print) | 131:205242 |
OpenAlex | W1999122596 |