Effect of Transition Metal Ions on Partial Ethane Oxidation in an Electrochemical System
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
Output data |
Year: 1999,
Volume: 66,
Number: 2,
Pages: 359-366
Pages count
: 8
DOI:
10.1007/BF02475813
|
Tags |
Ethane, Gas-diffusion electrode, Partial oxidation, Transition metal ions |
Authors |
Kuzmin A.O.
1
,
Savinova E.R.
1
,
Parmon V.N.
1
|
Affiliations |
1 |
Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
|
|
Funding (1)
1
|
International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union
|
93-2402 ext
|
Transition metal ions (Fe2+ and Cu2+) have been found to enhance the rate of ethane partial oxidation in a gas-liquid electrochemical reactor under mild conditions (363 K, atmospheric pressure). The effect is discussed in terms of a radical-chain mechanism involving OH radicals.