Kinetics of Oxidation of Butene-1 to Butanone in Aqueous Solution in the Presence of Ions Pd2+ and Mo-V-Phosphoric Heteropoly Acid Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
---|---|---|---|
Output data | Year: 2003, Volume: 80, Number: 1, Pages: 171-179 Pages count : 9 DOI: 10.1023/A:1026052813796 | ||
Tags | Butene-1, Mo-V-phosphoric heteropoly acids, Oxidation, Palladium | ||
Authors |
|
||
Affiliations |
|
Abstract:
Oxidation of butene-1 to butanone in the presence of homogeneous catalysts (PdSO4 + HPA-x), where HPA-x = H3+xPVxMo12-xO40, 1 £ x £ 4, was investigated. This reaction is found to be of the 1st order with respect to C4H8, and of the 0.64th order with respect to Pd. The reaction rate does not depend on the HPA-x concentration and pH of the solution. The activation energy of the reaction is variable. A kinetic expression of the reaction is obtained for 303-343 K.
Cite:
Zhizhina E.G.
, Simonova M.V.
, Odyakov V.F.
, Matveev K.I.
Kinetics of Oxidation of Butene-1 to Butanone in Aqueous Solution in the Presence of Ions Pd2+ and Mo-V-Phosphoric Heteropoly Acid
Reaction Kinetics and Catalysis Letters. 2003. V.80. N1. P.171-179. DOI: 10.1023/A:1026052813796 WOS Scopus РИНЦ
Kinetics of Oxidation of Butene-1 to Butanone in Aqueous Solution in the Presence of Ions Pd2+ and Mo-V-Phosphoric Heteropoly Acid
Reaction Kinetics and Catalysis Letters. 2003. V.80. N1. P.171-179. DOI: 10.1023/A:1026052813796 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 12, 2003 |
Accepted: | Jun 23, 2003 |
Published print: | Sep 1, 2003 |
Identifiers:
Web of science | WOS:000185987600023 |
Scopus | 2-s2.0-0142008058 |
Elibrary | 13435592 |
Chemical Abstracts | 2003:787842 |
Chemical Abstracts (print) | 140:113201 |
OpenAlex | W306737302 |