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Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands Review

Общее Language: Английский, Genre: Review,
Status: Published, Source type: Translated
Journal Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837
Output data Year: 2003, Volume: 72, Number: 9, Pages: 803-822 Pages count : 20 DOI: 10.1070/RC2003v072n09ABEH000822
Authors Tolstikov A.G. 1 , Khlebnikova T.B. 2 , Tolstikova O.V. 1 , Tolstikov G.A. 3
Affiliations
1 Institute of Technical Chemistry, Urals Branch of the Russian Academy of Sciences, ul. Lenina 13-a, 614000 Perm, Russian Federation
2 G K Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Acad. Lavrent'eva 5, 630090 Novosibirsk, Russian Federation
3 N N Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, prosp. Akad. Lavrent'eva 9, 630090 Novosibirsk, Russian Federation

Funding (1)

1 Council for Grants of the President of the Russian Federation НШ-2020.2003.3

Abstract: Methods for the synthesis of chiral organophosphorus compounds based on natural optically active compounds (hydroxy acids, amino acids and their derivatives, mono- and disaccharides, mono- and diterpenoids, steroids) are discussed. Particular attention is given to the synthesis of bisphosphines and bisphosphinites. These compounds serve as ligands for transition metal complexes, which catalyse asymmetric hydrogenation. Data on the enantioselectivity of hydrogenation of unsaturated precursors of amino acids and unsaturated prochiral acids as well as on information on the enantioselectivity of hydrosilylation of ketones are surveyed.
Cite: Tolstikov A.G. , Khlebnikova T.B. , Tolstikova O.V. , Tolstikov G.A.
Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands
Russian Chemical Reviews. 2003. V.72. N9. P.803-822. DOI: 10.1070/RC2003v072n09ABEH000822 publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Толстиков А.Г. , Хлебникова Т.Б. , Толстикова О.В. , Толстиков Г.А.
Природные соединения в синтезе хиральных фосфорорганических лигандов
Успехи химии. 2003. Т.72. №9. С.902-922. publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Dec 30, 2002
Published print: Sep 30, 2003
Published online: Oct 17, 2007
Identifiers:
publication_identifier.scopus_identifier_type 2-s2.0-12344329462
publication_identifier.rinz_identifier_type 13443628
publication_identifier.accession_number_identifier_type 2004:64777
publication_identifier.chemical_accession_number_identifier_type 140:253354
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