Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands
Review
| Общее |
Language:
Английский,
Genre:
Review,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Chemical Reviews
ISSN: 0036-021X
, E-ISSN: 1468-4837
|
| Output data |
Year: 2003,
Volume: 72,
Number: 9,
Pages: 803-822
Pages count
: 20
DOI:
10.1070/RC2003v072n09ABEH000822
|
| Authors |
Tolstikov A.G.
1
,
Khlebnikova T.B.
2
,
Tolstikova O.V.
1
,
Tolstikov G.A.
3
|
| Affiliations |
| 1 |
Institute of Technical Chemistry, Urals Branch of the Russian Academy of Sciences, ul. Lenina 13-a, 614000 Perm, Russian Federation
|
| 2 |
G K Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Acad. Lavrent'eva 5, 630090 Novosibirsk, Russian Federation
|
| 3 |
N N Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, prosp. Akad. Lavrent'eva 9, 630090 Novosibirsk, Russian Federation
|
|
Funding (1)
|
1
|
Council for Grants of the President of the Russian Federation
|
НШ-2020.2003.3
|
Methods for the synthesis of chiral organophosphorus compounds based on natural optically active compounds (hydroxy acids, amino acids and their derivatives, mono- and disaccharides, mono- and diterpenoids, steroids) are discussed. Particular attention is given to the synthesis of bisphosphines and bisphosphinites. These compounds serve as ligands for transition metal complexes, which catalyse asymmetric hydrogenation. Data on the enantioselectivity of hydrogenation of unsaturated precursors of amino acids and unsaturated prochiral acids as well as on information on the enantioselectivity of hydrosilylation of ketones are surveyed.