14N, 17O, 103Rh NMR Studies of Rh(III) State in Diluted Nitric Acid Solutions Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
||
---|---|---|---|
Output data | Year: 2002, Volume: 28, Number: 8, Pages: 573-580 Pages count : 8 DOI: 10.1023/A:1019761730495 | ||
Tags | Physical Chemistry; Chemical Shift; Nitric Acid; Acid Solution; HNO3 | ||
Authors |
|
||
Affiliations |
|
Funding (1)
1 | International Science and Technology Center | 1052-98 |
Abstract:
The state of rhodium(III) in nitric acid solutions diluted with 3M HNO3 or water was studied by 14N, 17O, and 103Rh NMR methods. The 103Rh NMR chemical shifts significantly depend on the ionic background of the solution. Concentrated nitric acid solutions (cRh = 0.5–1 mol/l) diluted 100 to 200 times retain the polynuclear Rh(III) forms with double (μ-NO3, μ-OH) bridges. The predominant form in the diluted solutions is a dimer.
Cite:
Fedotov M.A.
14N, 17O, 103Rh NMR Studies of Rh(III) State in Diluted Nitric Acid Solutions
Russian Journal of Coordination Chemistry. 2002. V.28. N8. P.573-580. DOI: 10.1023/A:1019761730495 WOS Scopus РИНЦ
14N, 17O, 103Rh NMR Studies of Rh(III) State in Diluted Nitric Acid Solutions
Russian Journal of Coordination Chemistry. 2002. V.28. N8. P.573-580. DOI: 10.1023/A:1019761730495 WOS Scopus РИНЦ
Original:
Федотов М.А.
О состоянии Rh(III) в разбавленных азотнокислых растворах по данным ЯМР 14N, 17O, 103Rh
Координационная химия. 2002. Т.28. №8. С.610-617. РИНЦ
О состоянии Rh(III) в разбавленных азотнокислых растворах по данным ЯМР 14N, 17O, 103Rh
Координационная химия. 2002. Т.28. №8. С.610-617. РИНЦ
Dates:
Submitted: | Jan 18, 2001 |
Published print: | Aug 1, 2002 |
Identifiers:
Web of science | WOS:000177848700009 |
Scopus | 2-s2.0-1842530098 |
Elibrary | 13393254 |
Chemical Abstracts | 2002:613286 |
Chemical Abstracts (print) | 138:45543 |
OpenAlex | W293912551 |