Intramolecular Interaction in Graphite Oxide Intercalation Compounds of Dodecahydro-Closo-Dodecaboric Acid under Heating Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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Output data | Year: 2005, Volume: 50, Number: 9, Pages: 1310-1314 Pages count : 5 | ||||
Tags | Carboxylic acids; Graphite; Heating; Infrared spectroscopy; Redox reactions; Thermogravimetric analysis; X ray diffraction analysis; X ray photoelectron spectroscopy | ||||
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Abstract:
Thermal conversions in graphite oxide intercalation compounds (GOICs) with dodecahydro-closo-dodecaboric acid were studied using chemical analysis, X-ray powder diffraction, thermogravimetry, and X-ray photoelectron and IR spectroscopy. The combination of an oxidizing agent (graphite oxide, GO) with a reducing agent (B12H122- anion) gives rise to an exothermic intramolecular redox interaction in these GOICs under heating. A mechanism of this interaction was suggested. The interaction can proceed quietly or be accompanied by an explosion and result in different sets of products depending on the composition of the GOIC and its thermal processing schedule.
Cite:
Saldin V.I.
, Tsvetnikov A.K.
, Ignatʹeva L.N.
, Nikolenko Y.M.
, Buznik V.M.
Intramolecular Interaction in Graphite Oxide Intercalation Compounds of Dodecahydro-Closo-Dodecaboric Acid under Heating
Russian Journal of Inorganic Chemistry. 2005. V.50. N9. P.1310-1314. WOS Scopus РИНЦ
Intramolecular Interaction in Graphite Oxide Intercalation Compounds of Dodecahydro-Closo-Dodecaboric Acid under Heating
Russian Journal of Inorganic Chemistry. 2005. V.50. N9. P.1310-1314. WOS Scopus РИНЦ
Original:
Салдин В.И.
, Цветников А.К.
, Игнатьева Л.Н.
, Николенко Ю.М.
, Бузник В.М.
Внутримолекулярные реакции в интеркалированных соединениях оксида графита с додекагидро-клозо-додекаборной кислотой при нагревании
Журнал неорганической химии. 2005. Т.50. №9. С.1412-1417. RSCI РИНЦ
Внутримолекулярные реакции в интеркалированных соединениях оксида графита с додекагидро-клозо-додекаборной кислотой при нагревании
Журнал неорганической химии. 2005. Т.50. №9. С.1412-1417. RSCI РИНЦ
Dates:
Submitted: | Nov 20, 2004 |
Published print: | Sep 1, 2005 |
Identifiers:
Web of science | WOS:000232022400004 |
Scopus | 2-s2.0-27344451993 |
Elibrary | 13475507 |