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Onset of Electrical Percolation in Onion-Like Carbon/Poly(methyl methacrylate) Composites Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Nanoscience and Nanotechnology Letters
ISSN: 1941-4900 , E-ISSN: 1941-4919
Output data Year: 2013, Volume: 5, Number: 11, Pages: 1201-1206 Pages count : 6 DOI: 10.1166/nnl.2013.1699
Tags Composite, Dielectric Properties, Electrical Percolation, Onion Like Carbon, PMMA
Authors Macutkevic J. 1 , Kuzhir P. 2 , Paddubskaya A. 2 , Banys J. 1 , Maksimenko S. 2 , Moseenkov S. 3 , Kuznetsov V.L. 3 , Shenderova O. 4 , Lambin Ph. 5
Affiliations
1 Vilniaus Universitetas
2 Belarusian State University
3 Boreskov Institute of Catalysis SB RAS
4 International Technology Center
5 University of Namur

Funding (3)

1 European Commission 266529 FP7-INCO-2010-6 BY-NANOERA
2 European Commission 318617 FP7-PEOPLE-2012-IRSES FAEMCAR
3 European Commission

Abstract: The results of broadband dielectric spectroscopy of onion-like carbon (OLC) based Poly(methyl methacrylate) (PMMA) composites are reported in wide temperature range 300–450 K. The dielectric properties of OLC/PMMA composites are chiefly dependent on the preparation technique, in particular annealing above the glass transition temperature of composite with 20 wt.% of OLC inclusions causes the vanishing of β relaxation, electrical conductivity appearance and onset of percolation. The percolation threshold in OLC/PMMA composites is found to be close to 20 wt.%. Below the percolation threshold the dielectric properties of composites in temperature range 300–420 K are determined mainly by β relaxation. The activation energy of such a relaxation is weakly dependent on OLC concentration.
Cite: Macutkevic J. , Kuzhir P. , Paddubskaya A. , Banys J. , Maksimenko S. , Moseenkov S. , Kuznetsov V.L. , Shenderova O. , Lambin P.
Onset of Electrical Percolation in Onion-Like Carbon/Poly(methyl methacrylate) Composites
Nanoscience and Nanotechnology Letters. 2013. V.5. N11. P.1201-1206. DOI: 10.1166/nnl.2013.1699 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Feb 11, 2013
Accepted: Feb 23, 2013
Published print: Nov 1, 2013
Identifiers:
publication_identifier.wos_identifier_type WOS:000328446700013
publication_identifier.scopus_identifier_type 2-s2.0-84890521577
publication_identifier.rinz_identifier_type 21901218
publication_identifier.accession_number_identifier_type 2013:1969913
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