Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies Full article
Journal |
Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255 |
||||||
---|---|---|---|---|---|---|---|
Output data | Year: 2013, Volume: 394, Pages: 656-662 Pages count : 7 DOI: 10.1016/j.ica.2012.07.028 | ||||||
Tags | Crystal structures, Dawson structure, Keggin structure, Polyoxometalates, Rhodium | ||||||
Authors |
|
||||||
Affiliations |
|
Funding (4)
1 | The Ministry of Education and Science of the Russian Federation | 11.519.11.3021 |
2 | Russian Foundation for Basic Research | 09-03-93105 |
3 | Haldor Topsoe A/S | |
4 | The Ministry of Education and Science of the Russian Federation | 14.740.11.0273 |
Abstract:
Reactions of non-lacunary Keggin ([PW12O40]3−) and Dawson ([α-P2W18O62]6−) polyoxometalates with rhodium (II) acetate have been studied. In the first case reaction yields the layered coordination polymer Li3[(Rh2(CH3COO)4)2(PW12O40)]·12.5 H2O (1), where polyoxoanions are coordinated via oxygen atoms to the {Rh2}4+ core. In the case of [α-P2W18O62]6− dirhodium clusters do not coordinate the polyoxoanion directly; however, they form K7[P2W18O62][Rh2(CH3COO)4X]·nH2O, where X = Cl, n = 11.37 (2); Br, n = 11.1 (3), which contain polymeric chain polyanions catena-[Rh2(CH3COO)4X]nn− (X = Cl, Br). Coordination polymer 1 is active in total oxidation of hydrogen and olefin at relatively low temperatures.
Cite:
Sokolov M.N.
, Adonin S.A.
, Peresypkina E.V.
, Abramov P.A.
, Smolentsev A.I.
, Potemkin D.I.
, Snytnikov P.V.
, Fedin V.P.
Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies
Inorganica Chimica Acta. 2013. V.394. P.656-662. DOI: 10.1016/j.ica.2012.07.028 WOS Scopus РИНЦ
Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies
Inorganica Chimica Acta. 2013. V.394. P.656-662. DOI: 10.1016/j.ica.2012.07.028 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 2, 2012 |
Accepted: | Jul 25, 2012 |
Published online: | Aug 17, 2012 |
Published print: | Jan 1, 2013 |
Identifiers:
Web of science | WOS:000311492900087 |
Scopus | 2-s2.0-84870245606 |
Elibrary | 20416059 |
Chemical Abstracts | 2012:1600077 |
Chemical Abstracts (print) | 158:64798 |
OpenAlex | W2022914607 |