The Kinetics of Oxidation of 1-Butene to Methylethylketone in the Presence of a Homogeneous Catalyst (Complex of Palladium+Mo-V-P Heteropoly Acid)
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Chemical Engineering Journal
ISSN: 1385-8947
, E-ISSN: 1873-3212
|
| Output data |
Year: 2013,
Volume: 230,
Pages: 308-313
Pages count
: 6
DOI:
10.1016/j.cej.2013.06.086
|
| Tags |
Butene-1 catalytic oxidation, Methylethylketone, Solutions of heteropoly acids, Tubular plug-flow reactor |
| Authors |
Zhizhina E.G.
1
,
Odyakov V.F.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
|
The kinetics of the direct oxidation of 1-butene to methylethylketone (MEK) is studied in the presence of the new homogeneous catalyst namely an aqueous solution of a Pd salt and Mo-V-P heteropoly acid having non-Keggin-type composition H12P3Mo18V7O85 (HPA-70). The catalyst (Pd + HPA-70) is characterized by an increased stability and high selectivity (>97%) in the MEK production. The process (1) is realized in two stages: (2) + (3). In stage (2), 1-butene reacts with the catalyst in a butylene reactor 1 with the formation of MEK and a reduced form of the catalyst. After stripping of the product, the reduced catalyst is oxidized by air in a reactor 2 under increased pressure (stage 3). The experimental data allowed us to obtain the kinetic equation for the reaction rate of 1-butene oxidation used for the calculation of the tubular plug-flow reactor 1.