Kinetic Study of Dimethylsulfide and Methanethiol Synthesis Full article
Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
||
---|---|---|---|
Output data | Year: 1994, Volume: 109, Number: 1, Pages: 45-61 Pages count : 17 DOI: 10.1016/0926-860X(94)85002-X | ||
Tags | aluminium oxide, dimethylsulfide, kinetic models, mechanism, methanethiol | ||
Authors |
|
||
Affiliations |
|
Abstract:
The kinetics of methanethiol and dimethyl sulfide decomposition as well as the interaction of methanol with methanethiol and hydrogen sulfide on aluminium oxide catalysts have been studied. Some general regularities in the reaction mechanisms have been revealed. These reactions appear to proceed by surface methoxylation followed by interaction of CH3O groups with methanethiol or H2S molecules activated on the surface, resulting in the desired products. Kinetic models for the reactions on a nonuniform catalyst surface have been proposed.
Cite:
Mashkin V.Y.
Kinetic Study of Dimethylsulfide and Methanethiol Synthesis
Applied Catalysis A: General. 1994. V.109. N1. P.45-61. DOI: 10.1016/0926-860X(94)85002-X WOS Scopus РИНЦ
Kinetic Study of Dimethylsulfide and Methanethiol Synthesis
Applied Catalysis A: General. 1994. V.109. N1. P.45-61. DOI: 10.1016/0926-860X(94)85002-X WOS Scopus РИНЦ
Dates:
Submitted: | Dec 11, 1992 |
Accepted: | Sep 3, 1993 |
Published print: | Feb 17, 1994 |
Published online: | Oct 22, 2001 |
Identifiers:
Web of science | WOS:A1994MY21900002 |
Scopus | 2-s2.0-0028375368 |
Elibrary | 31084713 |
Chemical Abstracts | 1994:190890 |
Chemical Abstracts (print) | 120:190890 |
OpenAlex | W1992799368 |