Intramolecular Spin Exchange in Palladium (II) Complexes with Imidazoline Nitroxyl Radicals Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1981, Volume: 30, Number: 8, Pages: 1433-1437 Pages count : 5 DOI: 10.1007/BF00952190 | ||||
Tags | Palladium; Halogen; Electron Spin; Spin Density; Halogen Atom | ||||
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Abstract:
Conclusions
1. The temperature dependence of the ESR spectra of solutions of Pd(II) complexes with imidazoline nitroxyl radicals PdL2 and [PdLX]2 (X=C1, Br, I) was investigated.
2. In all the investigated complexes the spin-exchange process is realized by an indirect mechanism.
3. A relation was established between the effectiveness of the delocalization of electron spin density and the nature of the bridging halogen atom and the structure of the chelating ligand (the nitroxyl radical).
Cite:
Kokorin A.I.
, Parmon V.N.
, Ovcharenko V.I.
, Larionov S.V.
, Volodarskij L.B.
Intramolecular Spin Exchange in Palladium (II) Complexes with Imidazoline Nitroxyl Radicals
Russian Chemical Bulletin. 1981. V.30. N8. P.1433-1437. DOI: 10.1007/BF00952190 WOS Scopus РИНЦ
Intramolecular Spin Exchange in Palladium (II) Complexes with Imidazoline Nitroxyl Radicals
Russian Chemical Bulletin. 1981. V.30. N8. P.1433-1437. DOI: 10.1007/BF00952190 WOS Scopus РИНЦ
Original:
Кокорин А.И.
, Пармон В.Н.
, Овчаренко В.И.
, Ларионов С.В.
, Володарский Л.Б.
Изучение внутримолекулярного спинового обмена в комплексах Pd (II) с имидазолиновыми нитроксильными радикалами
Известия Академии наук. Серия химическая. 1981. №8. С.1763-1768. РИНЦ
Изучение внутримолекулярного спинового обмена в комплексах Pd (II) с имидазолиновыми нитроксильными радикалами
Известия Академии наук. Серия химическая. 1981. №8. С.1763-1768. РИНЦ
Dates:
Submitted: | Dec 30, 1980 |
Published print: | Aug 1, 1981 |
Identifiers:
Web of science | WOS:A1981NR22700015 |
Scopus | 2-s2.0-34250234976 |
Elibrary | 30898681 |
OpenAlex | W2061231580 |