On the Origin of the Non-Faradaic Electrochemical Modification of Catalytic Activity (NEMCA) Phenomena. Oxygen Isotope Exchange on Pt Electrode in Cell with Solid Oxide Electrolyte Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 1993, Volume: 18, Number: 1-2, Pages: 153-164 Pages count : 12 DOI: 10.1007/BF00769508 | ||||
Tags | NEMCA phenomena, Oxygen isotope exchange, oxygen pumping, Pt electrode, solid oxide electrolyte | ||||
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Abstract:
Homomolecular oxygen exchange on Pt electrode in a zirconia electrochemical cell was studied. It was found that the current passing through the cell (O2− pumping through the electrolyte) does not change the rate of oxygen exchange on the Pt electrode with respect to its open circuit value, a fact that indicates that the strength of the chemisorptive bond of oxygen on the Pt electrode is invariant under open and closed circuit conditions.
Cite:
Sobyanin V.A.
, Sobolev V.I.
, Belyaev V.D.
, Mar'ina O.A.
, Demin A.K.
, Lipilin A.S.
On the Origin of the Non-Faradaic Electrochemical Modification of Catalytic Activity (NEMCA) Phenomena. Oxygen Isotope Exchange on Pt Electrode in Cell with Solid Oxide Electrolyte
Catalysis Letters. 1993. V.18. N1-2. P.153-164. DOI: 10.1007/BF00769508 WOS Scopus РИНЦ
On the Origin of the Non-Faradaic Electrochemical Modification of Catalytic Activity (NEMCA) Phenomena. Oxygen Isotope Exchange on Pt Electrode in Cell with Solid Oxide Electrolyte
Catalysis Letters. 1993. V.18. N1-2. P.153-164. DOI: 10.1007/BF00769508 WOS Scopus РИНЦ
Dates:
Submitted: | May 8, 1992 |
Accepted: | Nov 15, 1992 |
Published print: | Mar 1, 1993 |
Identifiers:
Web of science | WOS:A1993KQ56200017 |
Scopus | 2-s2.0-0043279957 |
Elibrary | 31187477 |
Chemical Abstracts | 1993:569108 |
Chemical Abstracts (print) | 119:169108 |
OpenAlex | W2094233844 |