Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid Full article
Journal |
International Journal of Chemical Kinetics
ISSN: 0538-8066 , E-ISSN: 1097-4601 |
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Output data | Year: 1992, Volume: 24, Number: 2, Pages: 145-154 Pages count : 10 DOI: 10.1002/kin.550240203 | ||||
Tags | AQUEOUS-SOLUTION; KINETICS; MECHANISM | ||||
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Abstract:
A study was made on the kinetics and mechanism of the reaction in aqueous solutions of 0.10 to 2.0 mol dm−3 alkaline concentrations. The substrates (S) applied were ethane-1,2-diol (ethylene glycol), glycol aldehyde, glycollic acid, and glyoxylic acid. Glycol aldehyde and glyoxylic acid were present in the form of dihydrate. In each case alkoxy anion is the reactive form and the KB constant of deprotonation can be calculated from the kinetic data. A mechanism based on electron abstraction is suggested. Manganate reacts with these substrates much slower than permanganate.
Cite:
Szammer J.
, Jáky M.
, Gerasimov O.V.
Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid
International Journal of Chemical Kinetics. 1992. V.24. N2. P.145-154. DOI: 10.1002/kin.550240203 WOS Scopus РИНЦ
Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid
International Journal of Chemical Kinetics. 1992. V.24. N2. P.145-154. DOI: 10.1002/kin.550240203 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 24, 1991 |
Accepted: | Jul 30, 1991 |
Published print: | Feb 1, 1992 |
Published online: | Sep 30, 2004 |
Identifiers:
Web of science | WOS:A1992HA79000002 |
Scopus | 2-s2.0-0026821251 |
Elibrary | 31124950 |
Chemical Abstracts | 1992:105447 |
Chemical Abstracts (print) | 116:105447 |
OpenAlex | W2117053743 |