Mechanism of Deamination of Butylamines on Protonic Centers of HNaY Zeolite Full article
Journal |
Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694 |
||
---|---|---|---|
Output data | Year: 1987, Volume: 104, Number: 1, Pages: 31-36 Pages count : 6 DOI: 10.1016/0021-9517(87)90333-2 | ||
Authors |
|
||
Affiliations |
|
Abstract:
IR spectroscopic studies of the interaction of tert-, sec-, and n-butylamines with HNaY protonic centers at 373–725 K and amine pressures of 13–133 kPa indicate that the deamination proceeds through intermediate butylammonium ions whose decomposition is the rate-determining step and which can provide ammonium ions directly. Energy diagrams have been plotted on the basis of calorimetric and thermodynamic data. The mechanism of the reaction is discussed.
Cite:
Malysheva L.V.
, Paukshtis E.A.
, Kotsarenko N.S.
Mechanism of Deamination of Butylamines on Protonic Centers of HNaY Zeolite
Journal of Catalysis. 1987. V.104. N1. P.31-36. DOI: 10.1016/0021-9517(87)90333-2 WOS Scopus РИНЦ
Mechanism of Deamination of Butylamines on Protonic Centers of HNaY Zeolite
Journal of Catalysis. 1987. V.104. N1. P.31-36. DOI: 10.1016/0021-9517(87)90333-2 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 2, 1986 |
Published print: | Mar 1, 1987 |
Published online: | May 24, 2004 |
Identifiers:
Web of science | WOS:A1987G451900003 |
Scopus | 2-s2.0-0008106407 |
Elibrary | 30809593 |
Chemical Abstracts | 1987:553714 |
Chemical Abstracts (print) | 107:153714 |
OpenAlex | W2036321525 |