SciAct
Toggle navigation
  • EN
  • RU

Sections:

  • Articles
  • Books
  • Conference attendances
  • Conference theses
  • Patents

Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102
Output data Year: 1986, Volume: 37, Number: 2-3, Pages: 177-188 Pages count : 12 DOI: 10.1016/0304-5102(86)85007-6
Authors Gusevskaya E.V. 1 , Beck I.E. 1 , Stepanov A.G. 1 , Likholobov V.A. 1 , Nekipelov V.M. 1 , Yermakov Yu.I. 1 , Zamaraev K.I. 1
Affiliations
1 Institute of Catalysis

Abstract: A detailed mechanism of ethylene oxidation by a palladium nitrite complex Pd(NO2)Cl(CH3CN)2 in chloroform solution is studied using IR and 1H NMR spectroscopy. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to end products are suggested.
Cite: Gusevskaya E.V. , Beck I.E. , Stepanov A.G. , Likholobov V.A. , Nekipelov V.M. , Yermakov Y.I. , Zamaraev K.I.
Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.37. N2-3. P.177-188. DOI: 10.1016/0304-5102(86)85007-6 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Nov 20, 1985
Accepted: Mar 21, 1986
Published print: Oct 1, 1986
Published online: Oct 2, 2001
Identifiers:
publication_identifier.wos_identifier_type WOS:A1986E458500006
publication_identifier.scopus_identifier_type 2-s2.0-0022790229
publication_identifier.rinz_identifier_type 30953939
publication_identifier.accession_number_identifier_type 1987:137780
publication_identifier.chemical_accession_number_identifier_type 106:137780
Altmetrics: