Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102
|
| Output data |
Year: 1986,
Volume: 37,
Number: 2-3,
Pages: 177-188
Pages count
: 12
DOI:
10.1016/0304-5102(86)85007-6
|
| Authors |
Gusevskaya E.V.
1
,
Beck I.E.
1
,
Stepanov A.G.
1
,
Likholobov V.A.
1
,
Nekipelov V.M.
1
,
Yermakov Yu.I.
1
,
Zamaraev K.I.
1
|
| Affiliations |
|
A detailed mechanism of ethylene oxidation by a palladium nitrite complex Pd(NO2)Cl(CH3CN)2 in chloroform solution is studied using IR and 1H NMR spectroscopy. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to end products are suggested.