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Nitro and Nitrato Palladium Complexes in Oxidation Processes: The Mechanism of the Formation of 1,1- and 1,2-addition Products during Ethylene Oxidation in Chloroform-Acetic Acid Solution Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102
Output data Year: 1992, Volume: 73, Number: 2, Pages: 115-146 Pages count : 32 DOI: 10.1016/0304-5102(92)80066-P
Tags OLEFINS; SYSTEM
Authors Beck I.E. 1 , Gusevskaya E.V. 1 , Stepanov A.G. 1 , Likholobov V.A. 1
Affiliations
1 Institute of Catalysis

Abstract: The stoichiometric oxidation of ethylene by Pd(NO(n))mCl2-mL2 complexes (where n = 2, 3; m = 0, 1, 2; L = CD3CN) in chloroform-acetic acid solution was studied with H-1 NMR. This reaction becomes catalytic in the presence of oxygen. The product distribution depends on the nature of the ligands and on the solvent composition. The reaction leads mostly to acetaldehyde, nitroethylene, ethylene glycol monoacetate, and 1,1-disubstituted ethanes. Kinetics and spectral data indicate the formation of a number of intermediates. The mechanism of ethylene oxidation to 1,1- and 1,2-addition products is discussed.
Cite: Beck I.E. , Gusevskaya E.V. , Stepanov A.G. , Likholobov V.A.
Nitro and Nitrato Palladium Complexes in Oxidation Processes: The Mechanism of the Formation of 1,1- and 1,2-addition Products during Ethylene Oxidation in Chloroform-Acetic Acid Solution
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1992. V.73. N2. P.115-146. DOI: 10.1016/0304-5102(92)80066-P publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Mar 1, 1991
Accepted: Dec 27, 1991
Published print: May 1, 1992
Published online: Oct 2, 2001
Identifiers:
publication_identifier.wos_identifier_type WOS:A1992JB04000001
publication_identifier.scopus_identifier_type 2-s2.0-0141783796
publication_identifier.rinz_identifier_type 31111169
publication_identifier.accession_number_identifier_type 1992:570611
publication_identifier.chemical_accession_number_identifier_type 117:170611
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