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Heterogeneous Structure of the Quaternary Metallic Glass Fe40Ni40P14B6: An EXAFS Investigation Full article

Journal Journal of Non-Crystalline Solids
ISSN: 0022-3093 , E-ISSN: 1873-4812
Output data Year: 1986, Volume: 86, Number: 3, Pages: 336-349 Pages count : 14 DOI: 10.1016/0022-3093(86)90022-0
Tags INTERMETALLICS - Amorphous; MATHEMATICAL TECHNIQUES - Algorithms
Authors Zschech E. 1 , Blau W. 1 , Kleinstück K. 1 , Hermann H. 2 , Mattern N. 2 , Kozlov M.A. 3 , Sheromov M.A. 4
Affiliations
1 Sektion Physik der Technischen Universitat Dresden, 8027 Dresden, GDR
2 Zentralinstitut fur Festkorperphysik und Werkstofforschung der Akademie der Wissenschaften der DDR, 8027 Dresden, GDR
3 Institute Kataliza Sibirskogo Otdelenija Akademii Nauk SSSR, 630090 Nowosibirsk, USSR
4 Institut Jadernoj Fiziki Sibirskogo Otdelenija Akadernii Nauk SSSR, 630090 Nowosibirsk, USSR

Abstract: The problems encountered in the analysis of EXAFS data from Fe40Ni40P14B6 are solved by assuming a micro-heterogeneous structure from chemically and structurally different micro-phases. A special Bayesian-type least-squares algorithm with general constraints was developed to reduce the effective number of free parameters, which fits simultaneously the EXAFS spectra at the NiK and the FeK edges and maximum prior knowledge as available. As a result of the analysis, the decomposition into micro-phase regions with Fe3B-type short-range order (52%) as well as random dense packed FeNiPB solid solution regions (48%) is proposed.
Cite: Zschech E. , Blau W. , Kleinstück K. , Hermann H. , Mattern N. , Kozlov M.A. , Sheromov M.A.
Heterogeneous Structure of the Quaternary Metallic Glass Fe40Ni40P14B6: An EXAFS Investigation
Journal of Non-Crystalline Solids. 1986. V.86. N3. P.336-349. DOI: 10.1016/0022-3093(86)90022-0 WOS Scopus РИНЦ
Dates:
Submitted: Oct 9, 1984
Accepted: Jan 8, 1986
Published print: Oct 1, 1986
Published online: Apr 17, 2003
Identifiers:
Web of science WOS:A1986E615800009
Scopus 2-s2.0-0022791453
Elibrary 31019612
Chemical Abstracts 1986:612451
Chemical Abstracts (print) 105:212451
OpenAlex W2091265658
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