Interaction of Copper Oxides with the Reaction Medium in Heterogeneous Catalytic-Oxidation of Carbon-Monoxide by Molecular-Oxygen. 2. Investigation of the Kinetics and Thermodynamics of Topochemical Transformations in Reduction of Cuprous-Oxide and a Copper Oxygen Solid-Solution Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1983, Volume: 24, Number: 4, Pages: 665-671 Pages count : 7 | ||
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Abstract:
The reduction of Cu2O and of Cu-O by CO was studied by a pulse microcatalytic method in a reactor. At 185°, the rate of reduction passes through a maximum with continuously-changing surface thermodynamic properties. The increase of the reduction rate is explained by a decrease of O surface bond energy with increasing reduction.
Cite:
Sadykov V.A.
, Tikhov S.F.
, Popovskii V.V.
, Bulgakov N.N.
Interaction of Copper Oxides with the Reaction Medium in Heterogeneous Catalytic-Oxidation of Carbon-Monoxide by Molecular-Oxygen. 2. Investigation of the Kinetics and Thermodynamics of Topochemical Transformations in Reduction of Cuprous-Oxide and a Copper Oxygen Solid-Solution
Kinetics and Catalysis. 1983. V.24. N4. P.665-671. WOS РИНЦ
Interaction of Copper Oxides with the Reaction Medium in Heterogeneous Catalytic-Oxidation of Carbon-Monoxide by Molecular-Oxygen. 2. Investigation of the Kinetics and Thermodynamics of Topochemical Transformations in Reduction of Cuprous-Oxide and a Copper Oxygen Solid-Solution
Kinetics and Catalysis. 1983. V.24. N4. P.665-671. WOS РИНЦ
Original:
Садыков В.А.
, Тихов С.Ф.
, Поповский В.В.
, Булгаков Н.Н.
Взаимодействие окислов меди с реакционной средой при гетерогенно-каталитическом окислении окиси углерода молекулярным кислородом. II. Исследование кинетики и термодинамики топохимических превращений при восстановлении закиси меди и твердого раствора медь-кислород
Кинетика и катализ. 1983. Т.24. №4. С.789-795. РИНЦ
Взаимодействие окислов меди с реакционной средой при гетерогенно-каталитическом окислении окиси углерода молекулярным кислородом. II. Исследование кинетики и термодинамики топохимических превращений при восстановлении закиси меди и твердого раствора медь-кислород
Кинетика и катализ. 1983. Т.24. №4. С.789-795. РИНЦ
Dates:
Submitted: | Dec 29, 1981 |
Published print: | Jul 1, 1983 |
Identifiers:
Web of science | WOS:A1983SQ13100003 |
Elibrary | 30602336 |