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Reactivity of Oxygen Adsorbed on Silver with Respect to Ethylene and the Modifying Action of Carbon-Dioxide. 2. Reactivity of the Adsorbed Layer of Oxygen in the Presence of Carbon-Dioxide Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1985, Volume: 26, Number: 6(2), Pages: 1293-1295 Pages count : 3
Authors Khasin A.V. , Boreskov G.K. , Bulushev D.A.
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: The modification of the adsorbed layer of oxygen on the surface of silver by carbon dioxide leads to a strong suppression of the processes of profound oxidation of ethylene and has little effect on the rate of oxidation of ethylene to ethylene oxide. The results of the investigation show that the adsorbablity of carbon dioxide passes through a maximum in the region theta equals 0. 15-0. 2 with changing coverage of the silver surface by oxygen. A similar result was also obtained in investigations on single crystals of silver. Close to the indicated region there are maximum values of the rates of profound and partial oxidation of ethylene, and the modifying action of CO2 is manifested to the greatest degree.
Cite: Khasin A.V. , Boreskov G.K. , Bulushev D.A.
Reactivity of Oxygen Adsorbed on Silver with Respect to Ethylene and the Modifying Action of Carbon-Dioxide. 2. Reactivity of the Adsorbed Layer of Oxygen in the Presence of Carbon-Dioxide
Kinetics and Catalysis. 1985. V.26. N6(2). P.1293-1295. publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Хасин А.В. , Боресков Г.К. , Булушев Д.А.
Реакционная способность кислорода, адсорбированного на серебре, в отношении этилена и модифицирующее действие диоксида углерода. II. Реакционная способность адсорбированного слоя кислорода в присутствии диоксида углерода
Кинетика и катализ. 1985. Т.26. №6. С.1500-1502. publication_identifier_short.rinz_identifier_type
Dates:
Published print: Nov 1, 1985
Identifiers:
publication_identifier.wos_identifier_type WOS:A1985D020700021
publication_identifier.scopus_identifier_type 2-s2.0-0022153523
publication_identifier.rinz_identifier_type 29669469