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π-Olefin-Palladium-Cuprate Complexes as Intermediates in the Formation of Propylene Glycol Monoacetate During the Oxidation of Propylene in PdCl2/CuCl2/HOAc Systems Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1990, Volume: 31, Number: 3, Pages: 506-510 Pages count : 5
Tags CHLORIDE
Authors Karandin A.V. 1 , Gusevskaya E.V. 1 , Likholobov V.A. 1 , Stepanov A.G. 1 , Talsi E.P. 1
Affiliations
1 Institute of Catalysis

Abstract: The mechanism of formation of propylene glycol monoacetate in the oxidation of propylene by molecular oxygen in a PdCl2/CuCl2/HOAc system was studied. The formation of olefin-palladium-cuprate complexes in the reaction solutions was established using NMR, EPR, and electron spectroscopy methods.
Cite: Karandin A.V. , Gusevskaya E.V. , Likholobov V.A. , Stepanov A.G. , Talsi E.P.
π-Olefin-Palladium-Cuprate Complexes as Intermediates in the Formation of Propylene Glycol Monoacetate During the Oxidation of Propylene in PdCl2/CuCl2/HOAc Systems
Kinetics and Catalysis. 1990. V.31. N3. P.506-510. publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Карандин А.В. , Гусевская Е.В. , Лихолобов В.А. , Степанов А.Г. , Талзи Е.П.
π-Олефин-палладий-купратные комплексы как интермедиаты в реакции образования пропиленгликольмоноацетата при окислении пропилена в системе PdCl2/CuCl2/HOAc
Кинетика и катализ. 1990. Т.31. №3. С.580-585. publication_identifier_short.rinz_identifier_type
Dates:
Published print: May 1, 1990
Identifiers:
publication_identifier.wos_identifier_type WOS:A1990EW73800011
publication_identifier.scopus_identifier_type 2-s2.0-0025513276
publication_identifier.rinz_identifier_type 31095249