π-Olefin-Palladium-Cuprate Complexes as Intermediates in the Formation of Propylene Glycol Monoacetate During the Oxidation of Propylene in PdCl2/CuCl2/HOAc Systems
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Output data |
Year: 1990,
Volume: 31,
Number: 3,
Pages: 506-510
Pages count
: 5
|
| Tags |
CHLORIDE |
| Authors |
Karandin A.V.
1
,
Gusevskaya E.V.
1
,
Likholobov V.A.
1
,
Stepanov A.G.
1
,
Talsi E.P.
1
|
| Affiliations |
|
The mechanism of formation of propylene glycol monoacetate in the oxidation of propylene by molecular oxygen in a PdCl2/CuCl2/HOAc system was studied. The formation of olefin-palladium-cuprate complexes in the reaction solutions was established using NMR, EPR, and electron spectroscopy methods.