195Pt and 119Sn NMR Studies of Pt-Sn Complexes in the Pt(II)-Sn(II)-i-C3H7OH System Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1983, Volume: 23, Number: 1-2, Pages: 21-23 Pages count : 3 DOI: 10.1007/BF02065657 | ||
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Abstract:
According to 195Pt and 119Sn NMR studies of the interaction of (C3H6)PtCl2 with SnCl2·2H2O in dehydrated isopropanol solution, three types of complexes with atomic ratios Pt:Sn=1∶5, 1∶2 and 1∶1, being in a dynamic equilibrium, have been revealed. A removal of the free HCl promotes the formation of the Pt:Sn=1∶2 complex.
Методом ЯМР на ядрах 195Pt и 119Sn изучено взаимодействие (C3H6)PtCl2 со SnCl2 2H2O в растворе абсолютированного изопропанола. Обнаружено три типа комплексов с атомным отношением Pt:Sn=1∶5, 1∶2 и 1∶1, находящихся между собой в подвижном равновесии. Удаление из раствора свободной HCl способствует образованию комплекса Pt:Sn=1∶2.
Cite:
Alt L.Y.
, Melnikova V.P.
, Startsev A.N.
, Duplyakin V.K.
195Pt and 119Sn NMR Studies of Pt-Sn Complexes in the Pt(II)-Sn(II)-i-C3H7OH System
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.21-23. DOI: 10.1007/BF02065657 WOS Scopus РИНЦ
195Pt and 119Sn NMR Studies of Pt-Sn Complexes in the Pt(II)-Sn(II)-i-C3H7OH System
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.21-23. DOI: 10.1007/BF02065657 WOS Scopus РИНЦ
Dates:
Submitted: | Oct 1, 1982 |
Accepted: | Jan 13, 1983 |
Published print: | Mar 1, 1983 |
Published online: | Aug 3, 2013 |
Identifiers:
Web of science | WOS:A1983SB83400005 |
Scopus | 2-s2.0-34250154458 |
Elibrary | 30924094 |
Chemical Abstracts | 1984:92204 |
Chemical Abstracts (print) | 100:92204 |
OpenAlex | W2028306427 |