Kinetic Study of Dioxygen Formation in Slightly Acidic Ru(bpy)33+ Solutions in the Presence of Monomeric and Dimeric Homogeneous Cobalt Catalysts Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1984, Volume: 26, Number: 1-2, Pages: 67-72 Pages count : 6 DOI: 10.1007/BF02063868 | ||
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Abstract:
The kinetics of Ru(bpy)33+ consumption and of O2 formation in phosphate (pH 5–7) and acetate (pH 5) buffers in the presence of CoCl2 and Co(NH3)n(H2O)6−n3+ (n=5, 4, 2) as catalysts have been studied. Dimeric forms of cobalt catalysts were found to be active in solutions of cobalt ammines. Inhibition of the reaction was detected upon substitution of H2O by D2O, as well as in acetate buffers as compared to phosphate buffers.
Cite:
Elizarova G.L.
, Matvienko L.G.
, Lozhkina N.V.
, Parmon V.N.
Kinetic Study of Dioxygen Formation in Slightly Acidic Ru(bpy)33+ Solutions in the Presence of Monomeric and Dimeric Homogeneous Cobalt Catalysts
Reaction Kinetics and Catalysis Letters. 1984. V.26. N1-2. P.67-72. DOI: 10.1007/BF02063868 WOS Scopus РИНЦ
Kinetic Study of Dioxygen Formation in Slightly Acidic Ru(bpy)33+ Solutions in the Presence of Monomeric and Dimeric Homogeneous Cobalt Catalysts
Reaction Kinetics and Catalysis Letters. 1984. V.26. N1-2. P.67-72. DOI: 10.1007/BF02063868 WOS Scopus РИНЦ
Dates:
Submitted: | Sep 22, 1983 |
Accepted: | Jan 17, 1984 |
Published print: | Mar 1, 1984 |
Identifiers:
Web of science | WOS:A1984ABA8600013 |
Scopus | 2-s2.0-34250136933 |
Elibrary | 31376293 |
Chemical Abstracts | 1985:138431 |
Chemical Abstracts (print) | 102:138431 |
OpenAlex | W2031711945 |