On the Mechanism of Hydrogen Oxidation on Layered Compounds of Graphite with Transition Metals
Full article
Common |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
Output data |
Year: 1985,
Volume: 29,
Number: 2,
Pages: 359-362
Pages count
: 4
DOI:
10.1007/BF02068527
|
Authors |
Ilchenko N.I.
1
,
Malyshev E.M.
2
,
Pankratiev Yu.D.
2
|
Affiliations |
1 |
Institute of Physical Chemistry, Kiev 252028
|
2 |
Institute of Catalysis, Novosibirsk 630090, USSR
|
|
Strongly bound oxygen separately adsorbed on LCG-M is inert with respect to H2. In catalysis with the simultaneous presence of O2 and H2, a weakly bound (presumably, molecular) form of oxygen participates. Catalytic reaction exerts a “protective” effect on LCG-M, inhibiting the strong dissociative chemisorption of oxygen.