Effect of Carbon Dioxide on the Catalytic Oxidation of Ethylene over Silver. Kinetic Reaction Model Accounting for the Modification of Catalyst Surface by Carbonate Groups

Effect of Carbon Dioxide on the Catalytic Oxidation of Ethylene over Silver. Kinetic Reaction Model Accounting for the Modification of Catalyst Surface by Carbonate Groups Full article

Общее

Language: Английский, Genre: Full article,
Status: Published, Source type: Original

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1991, Volume: 44, Number: 2, Pages: 463-468 Pages count : 6 DOI: 10.1007/BF02073016

Authors

Bulushev D.A.

¹ , Khasin A.V.

Affiliations

1	Institute of Catalysis, Novosibirsk 630090, USSR

Changes in the character of catalytic oxidation of ethylene over silver upon increasing pressure of reaction mixture, reflected in increased ethylene oxide selectivity, are due to the modifying effect of surface carbonate groups. A kinetic reaction model is suggested based on the individual investigations of reaction steps.

Bulushev D.A. , Khasin A.V.
Effect of Carbon Dioxide on the Catalytic Oxidation of Ethylene over Silver. Kinetic Reaction Model Accounting for the Modification of Catalyst Surface by Carbonate Groups
Reaction Kinetics and Catalysis Letters. 1991. V.44. N2. P.463-468. DOI: 10.1007/BF02073016 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type

Submitted:	Nov 19, 1990
Accepted:	Jan 10, 1991
Published print:	Aug 1, 1991

publication_identifier.wos_identifier_type	WOS:A1991FX19200027
publication_identifier.scopus_identifier_type	2-s2.0-0026202807
publication_identifier.rinz_identifier_type	31168979
publication_identifier.accession_number_identifier_type	1991:513886
publication_identifier.chemical_accession_number_identifier_type	115:113886