Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1992, Volume: 46, Number: 2, Pages: 263-269 Pages count : 7 DOI: 10.1007/BF02070944 | ||
Tags | Ether; Methanol; Physical Chemistry; Sulfide; Catalysis; Catalysis - Reaction Kinetics; Catalysts - Oxides; Mathematical Models; Methanol Hydrogen Sulfide | ||
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Abstract:
Kinetic regularities of dimethyl sulfide synthesis from methanol and H2S in the presence of WO3/Al2O3 have been studied under gradientless conditions. A stepwise mechanism of the reaction is suggested implying that methanol methoxylates the catalyst surface, the reaction of CH3O groups with H2S yields methylmercaptan and then dimethyl sulfide, whereas that with methanol produces dimethyl ether. The kinetic equations describe fairly well the process on inhomogeneous catalyst surface.
Cite:
Mashkin V.Y.
, Kudenkov V.M.
Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N2. P.263-269. DOI: 10.1007/BF02070944 WOS Scopus РИНЦ
Kinetic Studies of Dimethyl Sulfide Synthesis from Methanol and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N2. P.263-269. DOI: 10.1007/BF02070944 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 21, 1991 |
Accepted: | Oct 8, 1991 |
Published print: | Mar 1, 1992 |
Identifiers:
Web of science | WOS:A1992HM78000004 |
Scopus | 2-s2.0-0026832098 |
Elibrary | 31072289 |
Chemical Abstracts | 1992:235032 |
Chemical Abstracts (print) | 116:235032 |
OpenAlex | W2038192541 |