Hydrogen Activation on Copper Catalytic Sites in Stereoselective Alkyne Hydrogenation Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1995, Volume: 56, Number: 1, Pages: 77-86 Pages count : 10 DOI: 10.1007/BF02066953 | ||||
Tags | Hydrogen; Copper; Physical Chemistry; Catalysis; Atomic Hydrogen | ||||
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Abstract:
The interaction of hydrogen with copper clusters has been studied using EHM/AP method (extended Hückel method with Anderson's potential). Copper atoms are shown to form a dihydride structure with a high stability, which is due to the low mobility of atomic hydrogen on the surface. The formation of this complex appears to be favorable for concerted hydrogenation of acetylenes to cis-olefins.
Cite:
Yefremenko I.G.
, Zilberberg I.L.
, Zhidomirov G.M.
, Pak A.M.
Hydrogen Activation on Copper Catalytic Sites in Stereoselective Alkyne Hydrogenation
Reaction Kinetics and Catalysis Letters. 1995. V.56. N1. P.77-86. DOI: 10.1007/BF02066953 WOS Scopus РИНЦ
Hydrogen Activation on Copper Catalytic Sites in Stereoselective Alkyne Hydrogenation
Reaction Kinetics and Catalysis Letters. 1995. V.56. N1. P.77-86. DOI: 10.1007/BF02066953 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 5, 1995 |
Accepted: | Apr 10, 1995 |
Published print: | Oct 1, 1995 |
Identifiers:
Web of science | WOS:A1995TD10700009 |
Scopus | 2-s2.0-0042463408 |
Elibrary | 28439357 |
Chemical Abstracts | 1995:981387 |
Chemical Abstracts (print) | 124:175156 |
OpenAlex | W2089106816 |