Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1994, Volume: 43, Number: 7, Pages: 1142-1145 Pages count : 4 DOI: 10.1007/BF00698232 | ||
Tags | 2-methyl-1,4-naphthoqumone, 2-methyl-1-naphthol, heteropolyacids, oxidation, phase-transfer catalysis | ||
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Abstract:
2-Methyl-1-naphthol is oxidized into 2-methyl-1,4-naphthoquinone (menadione) by air in the presence of vanadomolybdophosphoric heteropolyacids and their salts. The reaction proceeds in a biphasic system, and the yield of menadione is up to 85 %. The influence of the composition of the heteropolyacids on the rate and the selectivity of the reaction was studied, and the reaction mechanism was proposed.
Cite:
Matveev K.I.
, Zhizhina E.G.
, Odyakov V.F.
, Parmon V.N.
Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids
Russian Chemical Bulletin. 1994. V.43. N7. P.1142-1145. DOI: 10.1007/BF00698232 WOS Scopus РИНЦ
Phase-Transfer Oxidation of 2-Methyl-1-Naphthol into 2-Methyl-1,4-Naphthoquinone in the Presence of Vanadomolybdophosphoric Heteropolyacids
Russian Chemical Bulletin. 1994. V.43. N7. P.1142-1145. DOI: 10.1007/BF00698232 WOS Scopus РИНЦ
Original:
Матвеев К.И.
, Жижина Е.Г.
, Одяков В.Ф.
, Пармон В.Н.
Окисление 2-метил-1-нафтола в 2-метил-1,4-нафтохинон методом межфазного катализа в присутствии ванадомолибдофосфорных гетерополикислот
Известия Академии наук. Серия химическая. 1994. №7. С.1208-1211. РИНЦ
Окисление 2-метил-1-нафтола в 2-метил-1,4-нафтохинон методом межфазного катализа в присутствии ванадомолибдофосфорных гетерополикислот
Известия Академии наук. Серия химическая. 1994. №7. С.1208-1211. РИНЦ
Dates:
Submitted: | Jul 26, 1993 |
Published print: | Jul 1, 1994 |
Identifiers:
Web of science | WOS:A1994QK21800007 |
Scopus | 2-s2.0-11544295498 |
Elibrary | 31101577 |
OpenAlex | W2073995871 |