Kinetics of Arylation of Olefins by Pd(OAc)2 in Benzene
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
| Output data |
Year: 1980,
Volume: 15,
Number: 1,
Pages: 49-54
Pages count
: 6
DOI:
10.1007/BF02062383
|
| Authors |
Kozhevnikov I.V.
1
,
Sharapova S.Ts.
1
|
| Affiliations |
| 1 |
Institute of Catalysis, Novosibirsk, USSR
|
|
Kinetics of phenylation of ethylene and styrene by Pd(OAc)2 in benzene at 95 °C is described by the equation W=k [PdII][PhH][Ol], kC2H4/kC2D4= =1.2±0.2, kPhH/kPhD=5.0±0.5. The reaction mechanism is discussed.