Mechanism of the Dehydrogenation of Formic Acid by Iridium and Rhodium Complexes Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1975, Volume: 2, Number: 1-2, Pages: 65-72 Pages count : 8 DOI: 10.1007/BF02060954 | ||
Tags | Physical Chemistry; Catalysis; Formic Acid; Reaction Mechanism; Dehydrogenation | ||
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Abstract:
The homogeneous catalytic process HCOOH→H2+CO2 has been studied in the presence of carbonyl-free phosphine complexes of iridium (I) and (III), and rhodium (I). The rupture of the C−H bond has been found to be the rate-determining step. The halide ion and phosphine are first substituted by formate ion in the coordination sphere of the metal. The reaction mechanism and its peculiarities are discussed.
Cite:
Yurtchenko E.N.
, Anikeenko N.P.
Mechanism of the Dehydrogenation of Formic Acid by Iridium and Rhodium Complexes
Reaction Kinetics and Catalysis Letters. 1975. V.2. N1-2. P.65-72. DOI: 10.1007/BF02060954 WOS Scopus РИНЦ
Mechanism of the Dehydrogenation of Formic Acid by Iridium and Rhodium Complexes
Reaction Kinetics and Catalysis Letters. 1975. V.2. N1-2. P.65-72. DOI: 10.1007/BF02060954 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 1, 1974 |
Published print: | Mar 1, 1975 |
Identifiers:
Web of science | WOS:A1975W268400009 |
Scopus | 2-s2.0-34250396785 |
Elibrary | 30886708 |
Chemical Abstracts | 1975:485431 |
Chemical Abstracts (print) | 83:85431 |
OpenAlex | W2017741188 |