Oxidative Coupling of Alkylbenzenes to Diaryls Catalyzed by the Palladium(II)-Heteropolyacid System
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
Output data |
Year: 1976,
Volume: 5,
Number: 4,
Pages: 401-406
Pages count
: 6
DOI:
10.1007/BF02060886
|
Authors |
Mennenga G.U.
1
,
Rudenkov A.I.
2
,
Matveev K.I.
2
,
Kozhevnikov I.V.
2
|
Affiliations |
1 |
Central Institute of Organic Chemistry, Rostock, GDR
|
2 |
Institute of Catalysis, Novosibirsk 630090, USSR
|
|
Oxidative coupling of alkylbenzenes (benzene, toluene, o-xylene, durene) is shown to proceed in the presence of palladium salts and heteropolyacids under the action of oxygen with a high yield of diaryls. The addition of mercury salts and variation of the solvent affect the reaction rate and isomer composition of the products.