Oxidative Coupling of Alkylbenzenes to Diaryls Catalyzed by the Palladium(II)-Heteropolyacid System

Oxidative Coupling of Alkylbenzenes to Diaryls Catalyzed by the Palladium(II)-Heteropolyacid System Full article

Общее

Language: Английский, Genre: Full article,
Status: Published, Source type: Original

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1976, Volume: 5, Number: 4, Pages: 401-406 Pages count : 6 DOI: 10.1007/BF02060886

Authors

Mennenga G.U. ¹ , Rudenkov A.I. ² , Matveev K.I.

² , Kozhevnikov I.V.

Affiliations

1	Central Institute of Organic Chemistry, Rostock, GDR
2	Institute of Catalysis, Novosibirsk 630090, USSR

Oxidative coupling of alkylbenzenes (benzene, toluene, o-xylene, durene) is shown to proceed in the presence of palladium salts and heteropolyacids under the action of oxygen with a high yield of diaryls. The addition of mercury salts and variation of the solvent affect the reaction rate and isomer composition of the products.

Mennenga G.U. , Rudenkov A.I. , Matveev K.I. , Kozhevnikov I.V.
Oxidative Coupling of Alkylbenzenes to Diaryls Catalyzed by the Palladium(II)-Heteropolyacid System
Reaction Kinetics and Catalysis Letters. 1976. V.5. N4. P.401-406. DOI: 10.1007/BF02060886 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type

Submitted:	May 21, 1976
Accepted:	Jul 13, 1976
Published print:	Dec 1, 1976

publication_identifier.wos_identifier_type	WOS:A1976CR21800004
publication_identifier.scopus_identifier_type	2-s2.0-0000721232
publication_identifier.rinz_identifier_type	30813557
publication_identifier.accession_number_identifier_type	1977:105719
publication_identifier.chemical_accession_number_identifier_type	86:105719