On the Mechanism of Propylene Oxidation over Gallium-Molybdenum Oxide Catalysts Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1976, Volume: 5, Number: 4, Pages: 407-413 Pages count : 7 DOI: 10.1007/BF02060887 | ||||
Tags | Oxidation; Oxygen; Physical Chemistry; Catalysis; Propylene | ||||
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Abstract:
The products of selective oxidation are shown to be formed via a stepwise mechanism with participation of surface allylic complexes. A successive transformation of π-allyl to σ-allyl and further to acrolein is possible. The products of complete oxidation may be formed through surface carbonate-carboxylate complexes via either a stepwise mechanism involving the catalyst's oxygen, or a concerted mechanism with the participation of molecular oxygen.
Cite:
Tichy J.
, Andrushkevich M.M.
, Boreskov G.K.
, Davidov A.A.
, Plyasova L.M.
, Sokolovskii V.D.
On the Mechanism of Propylene Oxidation over Gallium-Molybdenum Oxide Catalysts
Reaction Kinetics and Catalysis Letters. 1976. V.5. N4. P.407-413. DOI: 10.1007/BF02060887 WOS Scopus РИНЦ
On the Mechanism of Propylene Oxidation over Gallium-Molybdenum Oxide Catalysts
Reaction Kinetics and Catalysis Letters. 1976. V.5. N4. P.407-413. DOI: 10.1007/BF02060887 WOS Scopus РИНЦ
Dates:
Submitted: | May 27, 1976 |
Accepted: | Jul 13, 1976 |
Published print: | Dec 1, 1976 |
Identifiers:
Web of science | WOS:A1976CR21800005 |
Scopus | 2-s2.0-34250391911 |
Elibrary | 30834830 |
Chemical Abstracts | 1977:105560 |
Chemical Abstracts (print) | 86:105560 |
OpenAlex | W1989411920 |
publication.block.citing_info:
БД | Цитирований |
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Web of science | 1 |