Steady State Catalytic Properties and Oxygen Binding Energy of Cadmium-Molybdenum Catalysts in Methanol Oxidation Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1977, Volume: 7, Number: 2, Pages: 229-234 Pages count : 5 DOI: 10.1007/BF02061844 | ||
Tags | Oxidation; Oxygen; Methanol; Physical Chemistry; Formaldehyde | ||
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Abstract:
On normal cadmium molybdate the products of methanol oxidation are primarily CO2 and H2. After the introduction of excess MoO3 to reach Mo/Cd=1.2, methanol is oxidized to formaldehyde and carbon monoxide via a consecutive scheme. The oxygen binding energy in the steady state for the first sample is by 30 kcal/mol higher than that for the second catalyst. The activation energies of methanol conversion are 11.5 and 20 kcal/mol, respectively.
Cite:
Shkuratova L.N.
, Pankratiev Y.D.
, Popov B.I.
, Turkov V.M.
Steady State Catalytic Properties and Oxygen Binding Energy of Cadmium-Molybdenum Catalysts in Methanol Oxidation
Reaction Kinetics and Catalysis Letters. 1977. V.7. N2. P.229-234. DOI: 10.1007/BF02061844 WOS Scopus РИНЦ
Steady State Catalytic Properties and Oxygen Binding Energy of Cadmium-Molybdenum Catalysts in Methanol Oxidation
Reaction Kinetics and Catalysis Letters. 1977. V.7. N2. P.229-234. DOI: 10.1007/BF02061844 WOS Scopus РИНЦ
Dates:
Submitted: | Nov 5, 1976 |
Accepted: | Feb 23, 1977 |
Published print: | Jun 1, 1977 |
Identifiers:
Web of science | WOS:A1977DW14600019 |
Scopus | 2-s2.0-34250295819 |
Elibrary | 30917722 |
Chemical Abstracts | 1977:567214 |
Chemical Abstracts (print) | 87:167214 |
OpenAlex | W2061162948 |