Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid

Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid Full article

Общее

Language: Английский, Genre: Full article,
Status: Published, Source type: Original

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1977, Volume: 7, Number: 3, Pages: 291-296 Pages count : 6 DOI: 10.1007/BF02062458

Authors

Kozhevnikov I.V.

¹ , Mastikhin V.M.

¹ , Matveev K.I.

¹ , Kirichenko G.N. ² , Churkin Yu.V. ² , Glazunova V.I. ²

Affiliations

1	Institute of Catalysis, Novosibirsk, USSR
2	Institute of Petroleum Chemistry, Ufa, USSR

Using the NMR method, the kinetics of decomposition of isopropylbenzene hydroperoxide catalyzed by dodecamolybdophosphoric acid has been investigated in acetone at 22–50°C. The reaction is first order with respect to both the hydroperoxide and the catalyst, the activation energy is 14 kcal/mol. The data obtained are in agreement with the reaction mechanism suggested by Kharasch /1/.

Kozhevnikov I.V. , Mastikhin V.M. , Matveev K.I. , Kirichenko G.N. , Churkin Y.V. , Glazunova V.I.
Kinetics of Decomposition of Isopropylbenzene Hydroperoxide Catalyzed by Dodecamolybdophosphoric acid
Reaction Kinetics and Catalysis Letters. 1977. V.7. N3. P.291-296. DOI: 10.1007/BF02062458 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type

Submitted:	Jan 3, 1977
Accepted:	Feb 23, 1977
Published print:	Oct 1, 1977

publication_identifier.wos_identifier_type	WOS:A1977DZ87700009
publication_identifier.scopus_identifier_type	2-s2.0-5844378297
publication_identifier.rinz_identifier_type	30922049
publication_identifier.accession_number_identifier_type	1978:21819
publication_identifier.chemical_accession_number_identifier_type	88:21819