Influence of the Solvent on the Efficiency of Energy Transfer between Aromatic Molecules and Rare Earth Ions Full article
Journal |
Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X |
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Output data | Year: 1975, Volume: 9, Number: 4, Pages: 432-434 Pages count : 3 DOI: 10.1007/BF00523760 | ||
Tags | Rare Earth; Energy Transfer; Aromatic Molecule | ||
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Abstract:
We have previously shown [1, 2] that nonradiative transfer of electron excitation energy in solutions between aromatic molecules in the triplet (at) state and triply charged ions of a rare earth (IRE = Ln3+), and also the reverse process, are governed by exchange-resonance interactions. In these cases the transfer rate constant k t is appreciably lower than the diffusion constant and depends on delay of encounters of an excited donor and a nonexcited acceptor of energy due to formation of unstable complexes between the organic molecule (its heteroatom) and the IRE. The possibility of formation and the time of existence of these complexes should depend on the solvent, and therefore we have investigated the influence of change of solvent on the rate of energy transfer in the following processes.
Cite:
Ermolaev V.L.
, Tachin V.S.
Influence of the Solvent on the Efficiency of Energy Transfer between Aromatic Molecules and Rare Earth Ions
Theoretical and Experimental Chemistry. 1975. V.9. N4. P.432-434. DOI: 10.1007/BF00523760 Scopus РИНЦ
Influence of the Solvent on the Efficiency of Energy Transfer between Aromatic Molecules and Rare Earth Ions
Theoretical and Experimental Chemistry. 1975. V.9. N4. P.432-434. DOI: 10.1007/BF00523760 Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Ермолаев В.Л.
, Тачин В.С.
Влияние растворителя на эффективность переноса энергии между ароматическими молекулами и ионами редких земель
Теоретическая и экспериментальная химия. 1973. Т.9. №4. С.547-550. РИНЦ
Влияние растворителя на эффективность переноса энергии между ароматическими молекулами и ионами редких земель
Теоретическая и экспериментальная химия. 1973. Т.9. №4. С.547-550. РИНЦ
Dates:
Submitted: | Jun 5, 1972 |
Published print: | Jul 1, 1975 |
Identifiers:
Scopus | 2-s2.0-34250405055 |
Elibrary | 30888937 |
OpenAlex | W2082802169 |
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