The First Example of Ortho-Directing Effect of Weakly Coordinating Substituent [-BF3–] in the Catalytic Hydrodefluorination Reaction of Pentafluorophenyltrifluoroborate Anion
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Mendeleev Communications
ISSN: 0959-9436
, E-ISSN: 1364-551X
|
| Output data |
Year: 2009,
Volume: 19,
Number: 5,
Pages: 260-262
Pages count
: 3
DOI:
10.1016/j.mencom.2009.09.009
|
| Authors |
Adonin Nicolay Yu.
1
,
Prikhodko Sergey A.
1
,
Bardin Vadim V.
2
,
Parmon Valentin N.
1
|
| Affiliations |
| 1 |
G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
|
| 2 |
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
|
|
The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.