A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Angewandte Chemie - International Edition
ISSN: 1433-7851
, E-ISSN: 1521-3773
|
| Output data |
Year: 2006,
Volume: 45,
Number: 6,
Pages: 916-920
Pages count
: 5
DOI:
10.1002/anie.200503023
|
| Tags |
Chirality, Heterogeneous catalysis, Metal-organic frameworks, Microporous materials, Sorption |
| Authors |
Dybtsev Danil N.
1,2
,
Nuzhdin Alexey L.
3
,
Chun Hyungphil
1
,
Bryliakov Konstantin P.
3
,
Talsi Evgeniy P.
3
,
Fedin Vladimir P.
2
,
Kim Kimoon
1
|
| Affiliations |
| 1 |
National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784 (Republic of Korea)
|
| 2 |
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 3, Novosibirsk 630090 (Russia)
|
| 3 |
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)
|
|
Funding (2)
|
1
|
Russian Foundation for Basic Research
|
03-03-32009
|
|
2
|
Council for Grants of the President of the Russian Federation
|
МК-3842.2004.3
|
A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal–organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides.