Peculiarities of the Electronic Spectra of Model Cu–Zn Catalysts of Methanol Synthesis in the Oxidized and Reduced States
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Doklady Physical Chemistry
ISSN: 0012-5016
, E-ISSN: 1608-3121
|
| Output data |
Year: 2006,
Volume: 409,
Number: 1,
Pages: 193-197
Pages count
: 5
DOI:
10.1134/S0012501606070050
|
| Authors |
Khassin A.A.
1
,
Ruzankin S.F.
1
,
Anufrienko V.F.
1
,
Altynnikov A.A.
1
,
Larina T.V.
1
,
van den Heuvel J.
2
,
Yurieva T.M.
1
,
Parmon V.N.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
|
| 2 |
Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands
|
|
Funding (2)
|
1
|
Netherlands Organisation for Scientific Research
|
047.015.004
|
|
2
|
Russian Science Support Foundation
|
|
Solid solutions of copper cations in oxides of other metals are components of important catalysts. Nevertheless, despite the long history of studying such systems by various physicochemical methods, many features of their structure are not known. The investigation of the characteristics of their diffuse reflectance UV-Vis spectra presented in this paper shows a significant difference between the optical properties of the reduced forms of real Cu–Zn catalysts and those expected for the composition of copper metal nanoparticles and zinc oxide if there were no interaction between them.