Effects of Evaporation and Melting on Nonstoichiometry and Inhomogeneity of LiInSe2 Crystals Full article
Journal |
Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150 , E-ISSN: 1572-8943 |
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Output data | Year: 2007, Volume: 90, Number: 2, Pages: 601-605 Pages count : 5 DOI: 10.1007/s10973-006-7949-8 | ||||||
Tags | Evaporation, Evolved gas analysis, LiInSe2, Melting, Rapid thermal analysis | ||||||
Authors |
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Affiliations |
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Funding (3)
1 | Russian Foundation for Basic Research | 05-03-32236 |
2 | The Ministry of Education and Science of the Russian Federation | PD02-1.3-59 |
3 | Russian Foundation for Basic Research | 04-02-16334 |
Abstract:
Evaporation and compositional changes of the liquids above the melting point of LiInSe2 crystals have been characterized quantitatively by using special techniques of a rapid thermal analysis and differential dissolution. The occurrence of a liquid immiscible region in the Li2Se-rich side of the Li2Se-In2Se3 diagram and incongruent evaporation with the preferential evaporation of In2Se3 rising markedly above boiling point were determined from the peaks on the thermal curves and from precise control over the composition of the vapour and residual solid as a function of temperature. It was shown that both the processes could be the sources of nonstoichiometry and inhomogeneity of the LiInSe2 crystals.
Cite:
Vasilyeva I.G.
, Nikolaev R.E.
, Malakhov V.V.
, Isaenko L.I.
Effects of Evaporation and Melting on Nonstoichiometry and Inhomogeneity of LiInSe2 Crystals
Journal of Thermal Analysis and Calorimetry. 2007. V.90. N2. P.601-605. DOI: 10.1007/s10973-006-7949-8 WOS Scopus РИНЦ
Effects of Evaporation and Melting on Nonstoichiometry and Inhomogeneity of LiInSe2 Crystals
Journal of Thermal Analysis and Calorimetry. 2007. V.90. N2. P.601-605. DOI: 10.1007/s10973-006-7949-8 WOS Scopus РИНЦ
Dates:
Submitted: | Sep 2, 2006 |
Accepted: | Nov 16, 2006 |
Published online: | Feb 26, 2007 |
Published print: | Nov 1, 2007 |
Identifiers:
Web of science | WOS:000251088600045 |
Scopus | 2-s2.0-36849019953 |
Elibrary | 13547975 |
Chemical Abstracts | 2007:1418555 |
Chemical Abstracts (print) | 149:433785 |
OpenAlex | W2090861501 |