Catalytic Conversions of Dialkyl Disulfides Review
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2008, Volume: 49, Number: 6, Pages: 802-811 Pages count : 10 DOI: 10.1134/S0023158408060050 | ||
Tags | Thiophene; Methanethiol; Strong Basic Site; Vanadyl Acetylacetonate; Dialkyl Disulfide | ||
Authors |
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Affiliations |
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Abstract:
The results of the studies of catalytic conversions of lower dialkyl disulfides performed at the Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) are summarized. The selective hydrogenolysis of dimethyl and diethyl disulfides with the formation of alkanethiols occurs in a hydrogen medium on transition metal sulfides. Dimethyl disulfide turns into dimethyl sulfide in an inert gas medium on oxide catalysts with acid and basic sites on their surface. Lower dialkyl disulfides are dehydrocyclized to thiophene under the action of sulfide catalysts. In an oxygen medium on the metal oxides and salts, diethyl disulfide and a lower disulfide concentrate are selectively oxidized to form alkanethiolsulfinates, alkanethiolsulfonates, and alkanesulfonic acids.
Cite:
Mashkina A.V.
Catalytic Conversions of Dialkyl Disulfides
Kinetics and Catalysis. 2008. V.49. N6. P.802-811. DOI: 10.1134/S0023158408060050 WOS Scopus РИНЦ
Catalytic Conversions of Dialkyl Disulfides
Kinetics and Catalysis. 2008. V.49. N6. P.802-811. DOI: 10.1134/S0023158408060050 WOS Scopus РИНЦ
Original:
Машкина А.В.
Каталитические превращения диалкилдисульфидов
Кинетика и катализ. 2008. Т.49. №6. С.844-854. РИНЦ
Каталитические превращения диалкилдисульфидов
Кинетика и катализ. 2008. Т.49. №6. С.844-854. РИНЦ
Dates:
Submitted: | Feb 27, 2008 |
Published print: | Nov 1, 2008 |
Published online: | Dec 3, 2008 |
Identifiers:
Web of science | WOS:000261342700005 |
Scopus | 2-s2.0-57449110737 |
Elibrary | 13574561 |
Chemical Abstracts | 2008:1443225 |
Chemical Abstracts (print) | 151:56499 |
OpenAlex | W2048470908 |