X-ray Emission and X-ray Photoelectron Spectroscopic Studies of Fullerene Fluoride C60F24
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Physics of the Solid State
ISSN: 1063-7834
, E-ISSN: 1090-6460
|
| Output data |
Year: 2007,
Volume: 49,
Number: 6,
Pages: 1195-1200
Pages count
: 6
DOI:
10.1134/S1063783407060285
|
| Authors |
Lavskaya Y.V.
1
,
Okotrub A.V.
1
,
Bulusheva L.G.
1
,
Pazhetnov E.M.
2
,
Boronin A.I.
2
,
Denisenko N.I.
3
,
Boltalina O.V.
4
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS
|
| 2 |
Boreskov Institute of Catalysis SB RAS
|
| 3 |
Lomonosov Moscow State University
|
| 4 |
Colorado State University
|
|
Funding (2)
|
1
|
Council for Grants of the President of the Russian Federation
|
НШ-4419.2006.3
|
|
2
|
Volkswagen Foundation
|
855/I77
|
The structure of the fullerence fluoride C60F24 of the Th symmetry contains two types of chemically different carbon atoms, namely, atoms of isolated double bonds and atoms of CF groups. X-ray photoelectron and x-ray emission spectroscopic studies of C60F24 revealed a difference in the widths of the x-ray bands corresponding to these types of atoms. Nonempirical quantum-chemical calculations performed for C59NF24+ ions with a hole in the C 1s core level of the fullerence fluoride showed that the difference in the bandwidths may be due to the fact that the vibrational states of the system are different when 1s electrons are removed from chemically nonequivalent atoms.