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X-ray Emission and X-ray Photoelectron Spectroscopic Studies of Fullerene Fluoride C60F24 Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Physics of the Solid State
ISSN: 1063-7834 , E-ISSN: 1090-6460
Output data Year: 2007, Volume: 49, Number: 6, Pages: 1195-1200 Pages count : 6 DOI: 10.1134/S1063783407060285
Authors Lavskaya Y.V. 1 , Okotrub A.V. 1 , Bulusheva L.G. 1 , Pazhetnov E.M. 2 , Boronin A.I. 2 , Denisenko N.I. 3 , Boltalina O.V. 4
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS
2 Boreskov Institute of Catalysis SB RAS
3 Lomonosov Moscow State University
4 Colorado State University

Funding (2)

1 Council for Grants of the President of the Russian Federation НШ-4419.2006.3
2 Volkswagen Foundation 855/I77

Abstract: The structure of the fullerence fluoride C60F24 of the Th symmetry contains two types of chemically different carbon atoms, namely, atoms of isolated double bonds and atoms of CF groups. X-ray photoelectron and x-ray emission spectroscopic studies of C60F24 revealed a difference in the widths of the x-ray bands corresponding to these types of atoms. Nonempirical quantum-chemical calculations performed for C59NF24+ ions with a hole in the C 1s core level of the fullerence fluoride showed that the difference in the bandwidths may be due to the fact that the vibrational states of the system are different when 1s electrons are removed from chemically nonequivalent atoms.
Cite: Lavskaya Y.V. , Okotrub A.V. , Bulusheva L.G. , Pazhetnov E.M. , Boronin A.I. , Denisenko N.I. , Boltalina O.V.
X-ray Emission and X-ray Photoelectron Spectroscopic Studies of Fullerene Fluoride C60F24
Physics of the Solid State. 2007. V.49. N6. P.1195-1200. DOI: 10.1134/S1063783407060285 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Лавская Ю.В. , Окотруб А.В. , Булушева Л.Г. , Пажетнов Е.М. , Боронин А.И. , Денисенко Н.И. , Болталина О.В.
Рентгеноспектральное и рентгеноэлектронное исследование фторида фуллерена C60F24
Физика твердого тела. 2007. Т.49. №6. С.1135-1140. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Oct 11, 2006
Published print: Jun 1, 2007
Identifiers:
publication_identifier.wos_identifier_type WOS:000247601700028
publication_identifier.scopus_identifier_type 2-s2.0-36049021300
publication_identifier.rinz_identifier_type 13547828
publication_identifier.accession_number_identifier_type 2007:670809
publication_identifier.chemical_accession_number_identifier_type 147:352595
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