C4- Carbide Ligand in the Trigonal Prismatic Environment of Rheniums in [Re12CS17(CN)6]n- Complexes Full article
Journal |
Polyhedron
ISSN: 0277-5387 |
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Output data | Year: 2008, Volume: 27, Number: 14, Pages: 3167-3171 Pages count : 5 DOI: 10.1016/j.poly.2008.07.007 | ||||||
Tags | Carbon atom, ELF, Twelve nuclear rhenium clusters | ||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 08-03-00826 |
2 | Russian Foundation for Basic Research | 07-03-00912 |
Abstract:
The electronic state of carbon in trigonal prismatic environment in [Re12CS17(CN)6]n complexes with variable redox state n = 6 M 8 was studied by molecular orbital method and electron localization function. The state is characterized by sp2-hybridisation and oxidation state 4. A weak long-distance interaction between l6-C and l2-S in the group [(l6-C)(l2-S)3] was discovered for n = 6, the interaction disappears for n = 8.
Cite:
Kozlova S.G.
, Gabuda S.P.
, Slepkov V.A.
, Mironov Y.V.
, Fedorov V.E.
C4- Carbide Ligand in the Trigonal Prismatic Environment of Rheniums in [Re12CS17(CN)6]n- Complexes
Polyhedron. 2008. V.27. N14. P.3167-3171. DOI: 10.1016/j.poly.2008.07.007 WOS Scopus РИНЦ
C4- Carbide Ligand in the Trigonal Prismatic Environment of Rheniums in [Re12CS17(CN)6]n- Complexes
Polyhedron. 2008. V.27. N14. P.3167-3171. DOI: 10.1016/j.poly.2008.07.007 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 12, 2008 |
Accepted: | Jul 10, 2008 |
Published online: | Aug 26, 2008 |
Published print: | Sep 29, 2008 |
Identifiers:
Web of science | WOS:000259892200015 |
Scopus | 2-s2.0-51049089318 |
Elibrary | 13595093 |
Chemical Abstracts | 2008:1115217 |
Chemical Abstracts (print) | 149:542168 |
OpenAlex | W2072359145 |