New N-Allylated Monomers in the Synthesis of Practical Valuable High-Molecular-Weight Compounds Full article
Conference |
9th International Symposium on Polymers for Advanced Technologies 22-25 Oct 2007 , Shanghai |
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Journal |
Polymers for Advanced Technologies
ISSN: 1042-7147 , E-ISSN: 1099-1581 |
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Output data | Year: 2009, Volume: 20, Number: 3, Pages: 209-215 Pages count : 7 DOI: 10.1002/pat.1253 | ||||
Tags | Biological application of polymers, Kinetic regularities, N-containing allyl monomers, Physico-chemical properties, Radical polymerization | ||||
Authors |
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Abstract:
Methods for the synthesis of N-allylated monomers of new structural types based on transformations of hydrazides of
carboxylic acids and guanidine have been developed. A reactivity of N,N-diallyl-N(-acylhydrazines (DAH) and 2,2-
diallyl-1,1,3,3-tetraethylguanidiniumchloride (AGC) in reactions of free-radical homo- and copolymerization with sulfur dioxide and vinyl monomers has been studied. The structure of the polymers obtained was identified by NMR 13C. Investigations carried out showed DAH and AGC to copolymerize with vinyl monomers and sulphur dioxide, both double bonds participating with the formation of cis-, trans-stereoisomeric pyrrolidine structures in cyclolinear polymer chain. Kinetic regularities of the process and some properties of the copolymers have been investigated.
Cite:
Gorbunova M.N.
, Vorobʹeva A.
, Tolstikov A.G.
, Monakov Y.B.
New N-Allylated Monomers in the Synthesis of Practical Valuable High-Molecular-Weight Compounds
Polymers for Advanced Technologies. 2009. V.20. N3. P.209-215. DOI: 10.1002/pat.1253 WOS Scopus РИНЦ
New N-Allylated Monomers in the Synthesis of Practical Valuable High-Molecular-Weight Compounds
Polymers for Advanced Technologies. 2009. V.20. N3. P.209-215. DOI: 10.1002/pat.1253 WOS Scopus РИНЦ
Dates:
Submitted: | Nov 26, 2007 |
Accepted: | Jun 11, 2008 |
Published online: | Oct 10, 2008 |
Published print: | Mar 1, 2009 |
Identifiers:
Web of science | WOS:000264015300009 |
Scopus | 2-s2.0-67649416082 |
Elibrary | 13608151 |
Chemical Abstracts | 2009:321891 |
Chemical Abstracts (print) | 150:495194 |
OpenAlex | W2005591358 |