A Novel Method of the Synthesis of Molybdovanadophosphoric Heteropoly Acid Solutions
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
| Output data |
Year: 2008,
Volume: 95,
Number: 1,
Pages: 21-28
Pages count
: 8
DOI:
10.1007/s11144-008-5374-7
|
| Tags |
Catalysts, Mo-V-P heteropoly acids, Synthesis |
| Authors |
Odyakov Victor F.
1
,
Zhizhina Elena G.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis
|
|
A novel eco-friendly method of the synthesis of aqueous solutions of the Keggintype Mo-V-P heteropoly acids H3+x PV x Mo12−x O40 (HPA-x) is proposed. At the first stage, V2O5 is dissolved in cooled H2O2 to form peroxyvanadic compounds, which spontaneously decompose to yield a H6V10O28 solution. The latter is stabilized by the addition of H3PO4 to yield a H9PV14O42 solution that is added to a boiling aqueous suspension of (H3PO4 + MoO3). This suspension is gradually evaporated producing the HPA-x solution. This safe and practically wasteless method holds much promise for the preparation of HPA-x solutions with x = 2–6.