Unsaturated Sugars in Enantiospecific Synthesis of Natural Low-Molecular Bioregulators
and Their Structural Analogues
Russian Journal of Bioorganic Chemistry
, E-ISSN: 1608-330X
||α-2-deoxyglycosides, Glycals, Glycophosphingolipids, Levoglucosenone, Pheromones, Prostaglandin H2, Triterpenoids
Boreskov Institute of Catalysis SB RAS
Vorozhtzov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science
The review of works of the authors devoted to the synthesis of low-molecular bioregulators with the use of unsaturated sugars is presented. The schemes of synthesis of insect pheromones and acetogenins and glycophosphingolipids on the basis of glycals are discussed. The pathways of synthesis of triterpene 2-deoxy-α-glycosides are shown. The synthesis of prostanoids from levoglucosenone is considered.