Cu(II) and Cu(I) Complexes with 2-(3,5-Diphenyl-1H–pyrazole-1-yl)-4,6-diphenylpyrimidine:
Synthesis and Structure. Catalytic Activity of Cu(II) Compounds in Reaction of Ethylene Polymerization
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284
, E-ISSN: 1608-3318
|
| Output data |
Year: 2006,
Volume: 32,
Number: 3,
Pages: 199-207
Pages count
: 9
DOI:
10.1134/S1070328406030067
|
| Authors |
Bushuev M.B.
1
,
Krivopalov V.P.
2
,
Semikolenova N.V.
3
,
Peresypkina E.V.
1
,
Virovets A.V.
1
,
Sheludyakova L.A.
1
,
Lavrenova L.G.
1
,
Zakharov V.A.
3
,
Larionov S.V.
1
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS
|
| 2 |
Vorozhtzov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science
|
| 3 |
Boreskov Institute of Catalysis SB RAS
|
|
The Cu(II) and Cu(I) complexes with 2-(3,5-diphenyl-1 H -pyrazole-1-yl)-4,6-diphenylpyrimidine (L) of the composition CuLX 2 (X = Cl, Br) and CuL(MeCN)Br are synthesized. According to X-ray diffraction data, the complexes have molecular structures. The molecules L are coordinated to the copper atom in bidentate-cyclic mode, i.e., through the N 2 atom of pyrazole and N 1 atom of pyrimidine rings. The coordination polyhedron of the Cu 2+ ion in CuLX 2 compounds is completed to a distorted tetrahedron with halide ions, that of the Cu + ion in CuL(MeCN)Br compounds, with the bromide ion and the nitrogen atom of acetonitrile molecule. The CuLX 2 complexes (X = Cl, Br) in combination with cocatalysts (methylaluminoxane and triisobutylaluminium) exhibit catalytic activity in ethylene polymerization.