State of Rhodium(III) in Sulfuric Acid Solutions
Science article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284
, E-ISSN: 1608-3318
|
| Output data |
Year: 2007,
Volume: 33,
Number: 2,
Pages: 136-139
Pages count
: 4
DOI:
10.1134/S107032840702011X
|
| Authors |
Belyaev A.V.
1
,
Fedotov M.A.
2
,
Shagabutdinova S.N.
1
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS
|
| 2 |
Boreskov Institute of Catalysis SB RAS
|
|
The formation of rhodium(III) sulfate complexes under moderately rigorous temperature conditions was studied by 103Rh and 17O NMR spectroscopy. The complexes [Rh2(μ-SO4)2(H2O)8]2+, [Rh2(*μ-SO4)(H2O)8]4+, and [Rh3(μ-SO4)3(μ-OH)(H2O)10]2+ were found to be the most stable species in aged solutions.