The Study of Induced Aquation of Rh(III) Sulfate Complexes
Russian Journal of Coordination Chemistry
, E-ISSN: 1608-3318
Nikolaev Institute of Inorganic Chemistry SB RAS
Boreskov Institute of Catalysis SB RAS
The processes of aquation of Rh(III) complexes in the presence of BaCl2 and Ba(ClO4)2 were studied by the 103RH and 17O NMR methods. In the first case, the final products were found to be the monomeric aqua chloride complexes, while in the second case, aqua hydroxo complexes were formed. The chloride ions present in the system significantly increase the process rate.