Complexation of Rh(III) in Diluted Sulfuric Acid Solutions Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
||||||
---|---|---|---|---|---|---|---|
Output data | Year: 2007, Volume: 33, Number: 6, Pages: 449-453 Pages count : 5 DOI: 10.1134/S1070328407060103 | ||||||
Tags | Intramolecular Hydrogen Bond; Coordinate Water Molecule; Average Coordination Number; Double Sulfate; Interrelated System | ||||||
Authors |
|
||||||
Affiliations |
|
Abstract:
Complex formation in a system Rh(III)-H2SO4-H2O was studied by the 103Rh and 17O NMR spectroscopy at room temperature. The formation of two interrelated systems of mononuclear and polynuclear complexes was established in the above solutions. The predominant species in the first system is a labile ionic pair {Rh(H2O)63+ SO42−}+, while in the second system, two inert binuclear complexes [Rh2(μ-SO4)2(H2O)8]2+ and [Rh2(μ-SO4)(μ-OH)(H2O)8]3+ prevail.
Cite:
Belyaev A.V.
, Ilʹyashevich V.D.
, Pavlova E.I.
, Fedotov M.A.
, Shagabutdinova S.N.
Complexation of Rh(III) in Diluted Sulfuric Acid Solutions
Russian Journal of Coordination Chemistry. 2007. V.33. N6. P.449-453. DOI: 10.1134/S1070328407060103 WOS Scopus РИНЦ
Complexation of Rh(III) in Diluted Sulfuric Acid Solutions
Russian Journal of Coordination Chemistry. 2007. V.33. N6. P.449-453. DOI: 10.1134/S1070328407060103 WOS Scopus РИНЦ
Original:
Беляев А.В.
, Ильяшевич В.Д.
, Павлова Е.И.
, Федотов М.А.
, Шагабутдинова С.Н.
Комплексообразование Rh(III) в разбавленных растворах серной кислоты
Координационная химия. 2007. Т.33. №6. С.458-462. РИНЦ
Комплексообразование Rh(III) в разбавленных растворах серной кислоты
Координационная химия. 2007. Т.33. №6. С.458-462. РИНЦ
Dates:
Submitted: | Apr 19, 2006 |
Published print: | Jun 1, 2007 |
Identifiers:
Web of science | WOS:000247781400010 |
Scopus | 2-s2.0-34547325266 |
Elibrary | 13538090 |
Chemical Abstracts | 2007:742483 |
Chemical Abstracts (print) | 147:396938 |
OpenAlex | W1972215450 |