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The State of Al(III) in Alcohol Solutions of Aluminum Alkoxide as Probed by 27Al and 13C NMR and Small-Angle X-Ray Scattering Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613
Output data Year: 2008, Volume: 53, Number: 10, Pages: 1621-1627 Pages count : 7 DOI: 10.1134/S0036023608100161
Authors Fedotov M.A. 1 , Molchanov V.V. 1 , Zotov R. 1 , Tuzikov F.V. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: Solutions of aluminum alkoxides obtained by interaction of aluminum metal with methyl, ethyl, and isopropyl alcohols were studied by 27Al and 13C NMR and small-angle X-ray scattering. Alkoxides with a tetrahedral environment of aluminum prevail in methanol solutions, and those with an octahedral environment of aluminum predominate in ethanol solutions. In isopropyl alcohol at 293 K, polynuclear alkoxides with tetrahedral, octahedral, and pentacoordinated aluminum environments coexist. The structure of polynuclear complexes was refined by comparison of their calculated dimensions with small-angle X-ray scattering data.
Cite: Fedotov M.A. , Molchanov V.V. , Zotov R. , Tuzikov F.V.
The State of Al(III) in Alcohol Solutions of Aluminum Alkoxide as Probed by 27Al and 13C NMR and Small-Angle X-Ray Scattering
Russian Journal of Inorganic Chemistry. 2008. V.53. N10. P.1621-1627. DOI: 10.1134/S0036023608100161 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Федотов М.А. , Молчанов В.В. , Зотов Р.А. , Тузиков Ф.В.
О состоянии Al(III) в спиртовых растворах алкоксидов алюминия по данным ЯМР (27Al, 13C) и малоуглового рентгеновского рассеяния
Журнал неорганической химии. 2008. Т.53. №10. С.1735-1741. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Apr 24, 2007
Published print: Oct 1, 2008
Published online: Oct 14, 2008
Identifiers:
publication_identifier.wos_identifier_type WOS:000260018900016
publication_identifier.scopus_identifier_type 2-s2.0-54149096523
publication_identifier.rinz_identifier_type 13589906
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