Applications of Nuclear Magnetic Resonance to Study the Structure of Platinum-Group Metal Complexes in Aqueous Solutions Review
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2016, Volume: 57, Number: 3, Pages: 563-613 Pages count : 51 DOI: 10.1134/S0022476616030203 | ||
Tags | 103Rh, 105Pd, 187Os, 195Pt NMR, 99,101Ru, amino acid ligands, aqueous solutions, coordinate shift, inorganic ligands, platinum metal complexes, radioactive waste | ||
Authors |
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Abstract:
The review includes comprehensive NMR data on platinum metals (99,101Ru, 103Rh, 105Pd, 187Os, 195Pt) and ligand donor atoms (1H, 13C, 14,15N, 17O, 19F, 31P) of metal complexes in aqueous solutions. A systematic analysis of NMR spectroscopy techniques is presented with focus on the measurements of NMR parameters in these systems. A novel concept referred to as coordinate shift is introduced, allowing interpretation of NMR spectra of platinum metal complexes. The review contains an encyclopedic NMR database covering a period of over 50 years from the first measured NMR spectra of platinum metals to 2014.
Cite:
Fedotov M.A.
Applications of Nuclear Magnetic Resonance to Study the Structure of Platinum-Group Metal Complexes in Aqueous Solutions
Journal of Structural Chemistry. 2016. V.57. N3. P.563-613. DOI: 10.1134/S0022476616030203 WOS Scopus РИНЦ
Applications of Nuclear Magnetic Resonance to Study the Structure of Platinum-Group Metal Complexes in Aqueous Solutions
Journal of Structural Chemistry. 2016. V.57. N3. P.563-613. DOI: 10.1134/S0022476616030203 WOS Scopus РИНЦ
Original:
Федотов М.А.
Применение ядерного магнитного резонанса для исследования строения комплексов платиновых металлов в водных растворах
Журнал структурной химии. 2016. Т.57. №3. С.593-643. DOI: 10.15372/JSC20160320 RSCI РИНЦ
Применение ядерного магнитного резонанса для исследования строения комплексов платиновых металлов в водных растворах
Журнал структурной химии. 2016. Т.57. №3. С.593-643. DOI: 10.15372/JSC20160320 RSCI РИНЦ
Dates:
Submitted: | Feb 6, 2015 |
Published print: | May 1, 2016 |
Published online: | Jul 19, 2016 |
Identifiers:
Web of science | WOS:000380131700020 |
Scopus | 2-s2.0-84978924359 |
Elibrary | 27090909 |
Chemical Abstracts | 2016:1182582 |
OpenAlex | W2481614902 |